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Actinoids

Mediumchemistry

Compared to lanthanoids, actinoids show a wider range of oxidation states mainly because:

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About This Question

Subject
chemistry
Chapter
d- and f-block elements
Topic
actinoids
Difficulty
Medium
Year
2025
Tags
ActinoidsOxidation States5f Orbitals

Solution

Correct Answer:

5f, 6d and 7s orbitals are close in energy

In actinoids, the energies of 5f, 6d, and 7s orbitals are comparable. Therefore, varying numbers of electrons from these orbitals can participate in bonding, resulting in multiple oxidation states. Lanthanoids largely show +3 due to relatively less participation variability of 4f electrons. Thus orbital energy closeness explains the broader oxidation state range in actinoids.

This medium difficulty chemistry question is from the chapter d- and f-block elements, covering the topic of actinoids. It appeared in the 2025 exam.

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