Skip to content

Magnetic Moment Calculation

Hardchemistry

The Fe^3+ ion in an octahedral field with weak ligands has five unpaired electrons; what is its approximate spin-only magnetic moment?

Select the correct option:

🔒 Solution Hidden from View

Submit your answer to unlock the detailed step-by-step solution.

About This Question

Subject
chemistry
Chapter
d- and f-block elements
Topic
magnetic moment calculation
Difficulty
Hard
Year
2025
Tags
magnetic momentFe3+ ionhigh spinspin-only formulafive unpaired electrons

Solution

Correct Answer:

5.92 BM

The spin-only magnetic moment of a transition metal ion is given by μ = √(n(n+2)) Bohr magnetons, where n is the number of unpaired electrons. The Fe^3+ ion has the configuration 3d^5, and in a weak octahedral field the ligands cause little splitting, so all five d-electrons remain unpaired in a high-spin arrangement, giving n = 5. Substituting, μ = √(5(5+2)) = √(5 × 7) = √35 = 5.92 Bohr magnetons. This relatively high value reflects the maximum number of unpaired electrons possible for a d^5 ion. The option 1.73 BM corresponds to one unpaired electron. The option 3.87 BM corresponds to three unpaired electrons. The option 2.83 BM corresponds to two unpaired electrons, none of which match a high-spin d^5 ion. This calculation combining configuration and crystal field reasoning is a frequent JEE Advanced task. Carefully relating the data to the governing principle ensures the reasoning remains valid even when the numbers or species in the question are changed. Such questions reward conceptual clarity, since a student who truly grasps magnetic moment can solve many superficially different variants with the same approach. Plausibility check: substituting n = 5 reproduces √35 = 5.92 Bohr magnetons, the largest spin-only value for a first-series ion, confirming the answer.

This hard difficulty chemistry question is from the chapter d- and f-block elements, covering the topic of magnetic moment calculation. It appeared in the 2025 exam.

Looking for more practice? Explore all chemistry questions or browse d- and f-block elements questions on RankGuru.