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Actinide Vs Lanthanide

Mediumchemistry

Actinides differ from lanthanides mainly by:

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About This Question

Subject
chemistry
Chapter
d- and f-block elements
Topic
actinide vs lanthanide
Difficulty
Medium
Year
2025
Tags
ActinidesLanthanidesOxidation States

Solution

Correct Answer:

Greater tendency for multiple oxidation states

  1. Orbital Energy: In Lanthanides (), there is a significant energy gap between and . Thus, is the dominant oxidation state.
  2. Comparable Levels: In Actinides (), the energy difference between and orbitals is very small.
  3. Result: More electrons are available for bonding, allowing Actinides to show a wide range of oxidation states ( Neptunium and Plutonium show states up to ).
  4. Other Differences: Actinides have a higher tendency for complex formation and are all radioactive, unlike lanthanides (except Promethium).

This medium difficulty chemistry question is from the chapter d- and f-block elements, covering the topic of actinide vs lanthanide. It appeared in the 2025 exam.

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