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Iupac Nomenclature

Easychemistry

A chemist isolates a four-carbon straight chain bearing an aldehyde group at one terminal carbon; what is its correct IUPAC name?

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About This Question

Subject
chemistry
Chapter
some basic principles of organic chemistry
Topic
iupac nomenclature
Difficulty
Easy
Year
2025
Tags
IUPAC nomenclaturealdehyde suffixprincipal functional groupparent chain selectioncarbonyl naming

Solution

Correct Answer:

Butanal

In IUPAC nomenclature the principal functional group decides the suffix while the longest continuous carbon chain containing that group fixes the root name. An aldehyde group, -CHO, always occupies a terminal carbon and is denoted by the suffix '-al', with the carbonyl carbon automatically taking position 1. A continuous chain of four carbons gives the root 'but-', and combining the saturated parent 'butane' with the aldehyde suffix yields butanal. Butan-1-ol is wrong because that name belongs to an alcohol (-OH), not an aldehyde. Butanone is incorrect since it describes a ketone with the carbonyl on an internal carbon. Butanoic acid is wrong as -oic acid denotes a carboxylic acid (-COOH) rather than -CHO. This naming logic follows the NCERT rules for selecting the senior characteristic group and the longest parent chain. Sanity check: the -CHO group contributes one carbon, so a four-carbon aldehyde is CH_3CH_2CH_2CHO, consistent with butanal.

This easy difficulty chemistry question is from the chapter some basic principles of organic chemistry, covering the topic of iupac nomenclature. It appeared in the 2025 exam.

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