Iupac Nomenclature
What is the correct IUPAC name of [Cr(NH3)4Cl2]Cl?
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About This Question
- Subject
- chemistry
- Chapter
- coordination compounds
- Topic
- iupac nomenclature
- Difficulty
- Easy
- Year
- 2025
Solution
Correct Answer:
Tetraamminedichlorochromium(III) chloride
- Oxidation State Determination: Let x be the oxidation state of Cr. Ammonia (NH3) is neutral (0), and Chlorine (Cl) is −1.
- x+4(0)+2(−1)=+1 (due to the external Cl− ion).
- x−2=+1⟹x=+3. The metal is Chromium(III).
- Naming Ligands:
- 4 Ammonia molecules → tetraammine (alphabetically first).
- 2 Chlorine molecules within the sphere → dichloro.
- Metal Name: Since the complex cation is positive, we use the standard name chromium.
- Counter Ion: The external Cl− is named chloride.
- Final Name: Tetraamminedichlorochromium(III) chloride.
This easy difficulty chemistry question is from the chapter coordination compounds, covering the topic of iupac nomenclature. It appeared in the 2025 exam.
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