Inductive Effect
Replacing a hydrogen of acetic acid with a strongly electron-withdrawing chlorine atom changes its acid strength in which observable direction?
Select the correct option:
Solution
Acidity increases
The inductive effect is the permanent polarisation of sigma bonds caused by an electronegativity difference, transmitted through the chain with diminishing strength. A chlorine atom is electron-withdrawing and exerts a -I effect, pulling electron density away from the carboxyl group of the resulting chloroacetic acid. This stabilises the conjugate base, the carboxylate anion, by dispersing its negative charge, so the acid loses its proton more readily and acidity increases. The option that acidity decreases is wrong because only electron-donating (+I) groups would destabilise the anion and weaken the acid. The claim that acidity stays the same ignores the clear electronic perturbation introduced by chlorine. The idea that it becomes a base is incorrect since a carboxylic acid retains its acidic -COOH group regardless of substitution. This trend matches the NCERT ordering where chloroacetic acid is markedly stronger than acetic acid. Plausibility check: greater stabilisation of the negative conjugate base always corresponds to a stronger acid, consistent with increased acidity.
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More inductive effect Practice Questions
Which of the following α-halo carboxylic acids is the strongest acid due to the inductive effect of ...
Which of the following α-halo carboxylic acids is the strongest acid due to the inductive effect of ...
Which order correctly represents decreasing +I (electron donating) inductive effect?
Which order correctly represents decreasing +I (electron donating) inductive effect?
The -I (negative inductive) effect is shown by:
The -I (negative inductive) effect is shown by:
About This Question
- Subject
- chemistry
- Chapter
- some basic principles of organic chemistry
- Topic
- inductive effect
- Difficulty
- Easy
- Year
- 2025
Solution
Correct Answer:
Acidity increases
The inductive effect is the permanent polarisation of sigma bonds caused by an electronegativity difference, transmitted through the chain with diminishing strength. A chlorine atom is electron-withdrawing and exerts a -I effect, pulling electron density away from the carboxyl group of the resulting chloroacetic acid. This stabilises the conjugate base, the carboxylate anion, by dispersing its negative charge, so the acid loses its proton more readily and acidity increases. The option that acidity decreases is wrong because only electron-donating (+I) groups would destabilise the anion and weaken the acid. The claim that acidity stays the same ignores the clear electronic perturbation introduced by chlorine. The idea that it becomes a base is incorrect since a carboxylic acid retains its acidic -COOH group regardless of substitution. This trend matches the NCERT ordering where chloroacetic acid is markedly stronger than acetic acid. Plausibility check: greater stabilisation of the negative conjugate base always corresponds to a stronger acid, consistent with increased acidity.
This easy difficulty chemistry question is from the chapter some basic principles of organic chemistry, covering the topic of inductive effect. It appeared in the 2025 exam.
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