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Hydrogen Spectrum Series

Easychemistry

Which spectral series of hydrogen involves electron transitions to the n=3 level, and in which region of the electromagnetic spectrum does this series appear?

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About This Question

Subject
chemistry
Chapter
atomic structure
Topic
hydrogen spectrum series
Difficulty
Easy
Year
2025
Tags
Paschen serieshydrogen spectrumspectral seriesinfrared regionelectron transitions

Solution

Correct Answer:

Paschen series; infrared region

The hydrogen spectral series are named by the principal quantum number of the lower energy level to which electrons transition. The Lyman series involves transitions to n=1 and produces UV radiation. The Balmer series involves transitions to n=2 and produces visible (and near UV) radiation. The Paschen series involves transitions to n=3 from higher levels (n=4, 5, 6,...) and produces infrared radiation, since the energy gaps are relatively small. The Brackett series involves transitions to n=4 and produces far infrared radiation. Therefore, transitions to n=3 define the Paschen series in the infrared. Option (A) is wrong because Lyman series terminates at n=1, not n=3. Option (B) is wrong because Balmer series terminates at n=2, and it produces visible light. Option (D) is wrong because Brackett series terminates at n=4. The series classification and their spectral regions are directly covered in NCERT and are high-frequency JEE theory questions. Plausibility check: as the lower-level quantum number increases, transitions involve smaller energy gaps, so Paschen (n=3) lies at lower energy (longer wavelength) than Balmer (n=2), correctly placing it in the infrared region.

This easy difficulty chemistry question is from the chapter atomic structure, covering the topic of hydrogen spectrum series. It appeared in the 2025 exam.

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