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Valence Bond Theory And Resonance

Easychemistry

Benzene's bond length is uniform at 1.40 Å, intermediate between a C-C single bond and a C=C double bond; this observation is best explained by which concept?

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About This Question

Subject
chemistry
Chapter
chemical bonding and molecular structure
Topic
valence bond theory and resonance
Difficulty
Easy
Year
2025
Tags
resonancebenzene bond lengthpi electron delocalisationKekule structurearomatic stabilisation

Solution

Correct Answer:

Resonance or delocalisation of pi electrons

A C-C single bond typically has a bond length of 1.54 Å and a C=C double bond has a bond length of 1.34 Å. In benzene, all six C-C bond lengths are experimentally found to be 1.40 Å, which falls exactly between these two values. This uniform, intermediate bond length cannot be explained by a single Kekule structure, which would predict alternating single and double bonds. Instead, the concept of resonance explains that benzene is a hybrid of two Kekule structures (and other contributors), with the pi electrons delocalised equally over all six carbon atoms. This delocalisation makes every C-C bond equivalent and partially double-bond in character, explaining the observed bond length of 1.40 Å. The inductive effect involves sigma bond electron shifts and does not account for pi electron distribution or bond length uniformity. Hyperconjugation is relevant in alkyl-substituted systems and involves sigma-pi electron delocalisation, not the inherent pi system of benzene itself. sp^3 hybridisation would give tetrahedral carbon with no pi system at all, which contradicts benzene's planar structure. This concept is central to NCERT Class 11 and JEE questions on aromaticity and resonance. Plausibility: the resonance energy of benzene (approximately 152 kJ/mol) directly supports extensive pi electron delocalisation and the resulting bond equalisation.

This easy difficulty chemistry question is from the chapter chemical bonding and molecular structure, covering the topic of valence bond theory and resonance. It appeared in the 2025 exam.

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