Quantum Numbers
Approximate wavelength (nm) of the photon emitted when an electron in hydrogen atom drops from n=4 to n=2 (Balmer series):
Select the correct option:
Solution
486 nm
- Rydberg Equation: λ1=RHZ2(n121−n221).
- Constants: RH≈1.097×107 m⁻¹. For H, Z=1.
- Transition: n1=2 (Balmer series) and n2=4.
- Calculation:
- λ1=1.097×107(1/4−1/16)=1.097×107(3/16)
- λ≈486.2×10−9 m.
- Unit conversion: 486 nm.
- Identification: This is the Hβ line. The 3→2 transition (Hα) occurs at 656 nm.
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About This Question
- Subject
- chemistry
- Chapter
- atomic structure
- Topic
- quantum numbers
- Difficulty
- Medium
- Year
- 2025
Solution
Correct Answer:
486 nm
- Rydberg Equation: λ1=RHZ2(n121−n221).
- Constants: RH≈1.097×107 m⁻¹. For H, Z=1.
- Transition: n1=2 (Balmer series) and n2=4.
- Calculation:
- λ1=1.097×107(1/4−1/16)=1.097×107(3/16)
- λ≈486.2×10−9 m.
- Unit conversion: 486 nm.
- Identification: This is the Hβ line. The 3→2 transition (Hα) occurs at 656 nm.
This medium difficulty chemistry question is from the chapter atomic structure, covering the topic of quantum numbers. It appeared in the 2025 exam.
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