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Molecular Orbital Theory

Mediumchemistry

Which of the following species is expected to have the shortest bond length according to Molecular Orbital Theory?

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About This Question

Subject
chemistry
Chapter
chemical bonding and molecular structure
Topic
molecular orbital theory
Difficulty
Medium
Year
2025
Tags
molecular orbital theorybond orderbond lengthnitrogen speciesMO diagram

Solution

Correct Answer:

Bond length is inversely related to bond order: a higher bond order means a stronger, shorter bond. To compare these nitrogen species, we first calculate bond orders using MO theory. Neutral N_2 has 14 electrons: \sigma(1s)^2 \sigma^(1s)^2 \sigma(2s)^2 \sigma^(2s)^2 \pi(2p)^4 \sigma(2p_z)^2, giving bond order = (10 - 4)/2 = 3. N_2^+ has 13 electrons (one removed from \sigma(2p_z)), giving bond order = (9 - 4)/2 = 2.5. N_2^- has 15 electrons (one added to \pi^(2p)), giving bond order = (10 - 5)/2 = 2.5. N_2^{2+} has 12 electrons (two removed from the bonding \sigma(2p_z) orbital), giving bond order = (8 - 4)/2 = 2. Therefore the order of bond orders is: N_2 (3) > N_2^+ = N_2^- (2.5) > N_2^{2+} (2). Since bond length decreases as bond order increases, N_2 has the shortest bond length. Option N_2^+ is wrong because removing an electron from the bonding \sigma(2p_z) orbital reduces bond order from 3 to 2.5. Option N_2^- adds an electron to an antibonding \pi^ orbital, also reducing bond order to 2.5. Option N_2^{2+} loses two bonding electrons, further reducing bond order to 2. This is a fundamental JEE MO theory application from NCERT Class 11. Verification: the experimental N≡N bond length is 110 pm, the shortest among all nitrogen species listed, consistent with a bond order of 3.

This medium difficulty chemistry question is from the chapter chemical bonding and molecular structure, covering the topic of molecular orbital theory. It appeared in the 2025 exam.

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