Magnetic Properties
[Fe(CN)6]4− magnetic character is best described as:
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About This Question
- Subject
- chemistry
- Chapter
- coordination compounds
- Topic
- magnetic properties
- Difficulty
- Medium
- Year
- 2025
Solution
Correct Answer:
Diamagnetic
- Electronic State: Fe2+ has a d6 configuration.
- Ligand Field: CN− is a very strong field ligand (High splitting, Δo>>P).
- Filling Pattern: To avoid the high energy of the eg orbitals, all six electrons fill and pair up in the lower t2g orbitals (t2g6eg0).
- Observations: Since all electrons are paired, there is no net magnetic moment.
- Conclusion: The complex is diamagnetic.
This medium difficulty chemistry question is from the chapter coordination compounds, covering the topic of magnetic properties. It appeared in the 2025 exam.
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