Degree Of Unsaturation
A hydrocarbon with the molecular formula C6H10 is being analysed, and the total number of degrees of unsaturation present in the molecule must be determined.
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Solution
2
The degree of unsaturation, also called the index of hydrogen deficiency, counts how many rings plus pi bonds a molecule contains and is found from the formula DoU=(2C+2−H)/2 for a compound of carbon and hydrogen only. Substituting C=6 and H=10 gives DoU=(2×6+2−10)/2=(12+2−10)/2=4/2=2. So the molecule has two degrees of unsaturation, which could be two double bonds, one triple bond, one ring plus one double bond, or two rings. A value of 1 is wrong because it would correspond to formula C6H12, which has two more hydrogens. A value of 3 is incorrect since it would require formula C6H8 with two fewer hydrogens. A value of 0 would describe a fully saturated acyclic alkane C6H14, which does not match the given formula. This is the standard NCERT and JEE method of relating formula to unsaturation. A plausibility check: each missing pair of hydrogens relative to the saturated alkane corresponds to one degree of unsaturation, and C6H14 minus C6H10 is four hydrogens, giving two.
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About This Question
- Subject
- chemistry
- Chapter
- hydrocarbons
- Topic
- degree of unsaturation
- Difficulty
- Easy
- Year
- 2025
Solution
Correct Answer:
2
The degree of unsaturation, also called the index of hydrogen deficiency, counts how many rings plus pi bonds a molecule contains and is found from the formula DoU=(2C+2−H)/2 for a compound of carbon and hydrogen only. Substituting C=6 and H=10 gives DoU=(2×6+2−10)/2=(12+2−10)/2=4/2=2. So the molecule has two degrees of unsaturation, which could be two double bonds, one triple bond, one ring plus one double bond, or two rings. A value of 1 is wrong because it would correspond to formula C6H12, which has two more hydrogens. A value of 3 is incorrect since it would require formula C6H8 with two fewer hydrogens. A value of 0 would describe a fully saturated acyclic alkane C6H14, which does not match the given formula. This is the standard NCERT and JEE method of relating formula to unsaturation. A plausibility check: each missing pair of hydrogens relative to the saturated alkane corresponds to one degree of unsaturation, and C6H14 minus C6H10 is four hydrogens, giving two.
This easy difficulty chemistry question is from the chapter hydrocarbons, covering the topic of degree of unsaturation. It appeared in the 2025 exam.
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