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Degree Of Unsaturation

Easychemistry

A hydrocarbon with the molecular formula is being analysed, and the total number of degrees of unsaturation present in the molecule must be determined.

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About This Question

Subject
chemistry
Chapter
hydrocarbons
Topic
degree of unsaturation
Difficulty
Easy
Year
2025
Tags
degree of unsaturationindex of hydrogen deficiencymolecular formula analysisrings and pi bondsstructure prediction

Solution

Correct Answer:

The degree of unsaturation, also called the index of hydrogen deficiency, counts how many rings plus pi bonds a molecule contains and is found from the formula for a compound of carbon and hydrogen only. Substituting and gives . So the molecule has two degrees of unsaturation, which could be two double bonds, one triple bond, one ring plus one double bond, or two rings. A value of is wrong because it would correspond to formula , which has two more hydrogens. A value of is incorrect since it would require formula with two fewer hydrogens. A value of would describe a fully saturated acyclic alkane , which does not match the given formula. This is the standard NCERT and JEE method of relating formula to unsaturation. A plausibility check: each missing pair of hydrogens relative to the saturated alkane corresponds to one degree of unsaturation, and minus is four hydrogens, giving two.

This easy difficulty chemistry question is from the chapter hydrocarbons, covering the topic of degree of unsaturation. It appeared in the 2025 exam.

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