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Azeotropes

Mediumchemistry

An azeotropic mixture of ethanol and water boils at:

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About This Question

Subject
chemistry
Chapter
solutions
Topic
azeotropes
Difficulty
Medium
Year
2025
Tags
AzeotropesDistillationPhase Diagrams

Solution

Correct Answer:

78.5°C (constant composition)

An Azeotrope is a 'constant boiling mixture' that has the same composition in the liquid and vapor phases.

  • Ethanol and water form a Minimum Boiling Azeotrope at ethanol and water by mass.
  • This mixture boils at (often rounded to ), which is lower than the boiling points of both pure ethanol () and pure water (). Because the composition does not change during boiling, they cannot be further separated by simple fractional distillation.

This medium difficulty chemistry question is from the chapter solutions, covering the topic of azeotropes. It appeared in the 2025 exam.

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