Work In A Polytropic Cycle
One mole of an ideal monatomic gas is heated at constant volume so its absolute temperature doubles from 300 K to 600 K. Taking R=8.31 J mol−1K−1, how much heat must be supplied?
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Solution
3740 J
Because the volume is held constant, the process is isochoric, so the gas does no work and the First Law reduces to Q=Δcup=nCVΔT. For a monatomic ideal gas CV=23R, since it has three translational degrees of freedom each contributing 21R. Substituting n=1, CV=23(8.31)=12.47 J mol−1K−1, and ΔT=600−300=300 K gives Q=1×12.47×300≈3740 J. The value 6232 J wrongly uses CP=25R, appropriate for constant pressure, not constant volume. The value 2494 J uses R alone without the factor 23. The value 1247 J halves the correct CV contribution. Since no work is done, all supplied heat raises internal energy, so Q equals ΔU exactly. Had the same temperature rise been carried out at constant pressure instead, more heat would be required because part of it would go into expansion work, illustrating why CP exceeds CV by R. As a magnitude check, doubling the temperature of one mole of monatomic gas should add a few kilojoules of internal energy, and 3740 J sits squarely in that expected range.
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About This Question
- Subject
- physics
- Chapter
- thermodynamics
- Topic
- work in a polytropic cycle
- Difficulty
- Hard
- Year
- 2025
Solution
Correct Answer:
3740 J
Because the volume is held constant, the process is isochoric, so the gas does no work and the First Law reduces to Q=Δcup=nCVΔT. For a monatomic ideal gas CV=23R, since it has three translational degrees of freedom each contributing 21R. Substituting n=1, CV=23(8.31)=12.47 J mol−1K−1, and ΔT=600−300=300 K gives Q=1×12.47×300≈3740 J. The value 6232 J wrongly uses CP=25R, appropriate for constant pressure, not constant volume. The value 2494 J uses R alone without the factor 23. The value 1247 J halves the correct CV contribution. Since no work is done, all supplied heat raises internal energy, so Q equals ΔU exactly. Had the same temperature rise been carried out at constant pressure instead, more heat would be required because part of it would go into expansion work, illustrating why CP exceeds CV by R. As a magnitude check, doubling the temperature of one mole of monatomic gas should add a few kilojoules of internal energy, and 3740 J sits squarely in that expected range.
This hard difficulty physics question is from the chapter thermodynamics, covering the topic of work in a polytropic cycle. It appeared in the 2025 exam.
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