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Werner's Theory

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According to Werner's theory, in [Co(NH₃)₆]Cl₃, the coordination number of Co is:

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About This Question

Subject
chemistry
Chapter
coordination compounds
Topic
werner's theory
Difficulty
Easy
Year
2025
Tags
Werner's TheoryCoordination NumberComplexes

Solution

Correct Answer:

6

According to Werner's Coordination Theory:

  1. Primary Valence: Ionizable valence (oxidation state). For , it is . Cl⁻ ions satisfy this.
  2. Secondary Valence: Non-ionizable valence (Coordination Number). It represents the number of ligand donor atoms bonded to the metal.
  • In , the species inside the square brackets constitute the coordination sphere.
  • Six nitrogen atoms from six molecules are directly coordinated to the Cobalt center.
  • Therefore, the coordination number is 6.

This easy difficulty chemistry question is from the chapter coordination compounds, covering the topic of werner's theory. It appeared in the 2025 exam.

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