Vbt
Hardchemistry
The hybridization of Ni in [Ni(CN)₄]²⁻ is:
Select the correct option:
Solution
Incorrect! Answer:
dsp²
- Ni²⁺ configuration: Nickel (Z=28) is [Ar]3d84s2. Ni²⁺ is [Ar]3d8.
- Ligand Influence: CN− is a strong field ligand. According to Valence Bond Theory, it causes the pairing of the two unpaired electrons in the 3d shell.
- Hybridization: Pairing clears one 3d orbital. The metal uses 1 inner 3d orbital, 1 4s orbital, and 2 4p orbitals for bonding.
- Hybridization: dsp2.
- Geometry: Square Planar.
- The complex is diamagnetic (no unpaired electrons).
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About This Question
- Subject
- chemistry
- Chapter
- coordination compounds
- Topic
- vbt
- Difficulty
- Hard
- Year
- 2025
This hard difficulty chemistry question is from the chapter coordination compounds, covering the topic of vbt. It appeared in the 2025 exam. Practice this and similar questions to strengthen your understanding of coordination compounds concepts.
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