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Vbt

Hardchemistry

The hybridization of Ni in [Ni(CN)₄]²⁻ is:

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About This Question

Subject
chemistry
Chapter
coordination compounds
Topic
vbt
Difficulty
Hard
Year
2025
Tags
VBTHybridizationSquare Planar

Solution

Correct Answer:

dsp²

  1. Ni²⁺ configuration: Nickel () is . Ni²⁺ is .
  2. Ligand Influence: is a strong field ligand. According to Valence Bond Theory, it causes the pairing of the two unpaired electrons in the shell.
  3. Hybridization: Pairing clears one orbital. The metal uses inner orbital, orbital, and orbitals for bonding.
  • Hybridization: .
  • Geometry: Square Planar.
  • The complex is diamagnetic (no unpaired electrons).

This hard difficulty chemistry question is from the chapter coordination compounds, covering the topic of vbt. It appeared in the 2025 exam.

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