Specific Heats And Mayer's Relation
For one mole of any ideal gas, the difference between the molar specific heat at constant pressure and that at constant volume equals which fundamental quantity?
Select the correct option:
Solution
R
Connecting the two principal molar specific heats of an ideal gas, Mayer's relation states Cp−Cv=R, where R is the universal gas constant. The physical reason is that heating a gas at constant volume raises only its internal energy, while heating at constant pressure also requires the gas to do work PΔV on its surroundings as it expands. The extra heat needed per mole per kelvin for this expansion work is exactly R. Therefore the difference equals R. The option R/2 wrongly associates the difference with a single degree of freedom. The option 2R doubles the expansion work, which has no physical basis. The option 3R/2 confuses the difference with the constant-volume specific heat of a monatomic gas. This is the standard NCERT result derived from the first law of thermodynamics applied to ideal gases. As a check, both Cp and Cv depend on degrees of freedom, yet their difference is universally R for every ideal gas, regardless of molecular structure.
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About This Question
- Subject
- physics
- Chapter
- kinetic theory of gases
- Topic
- specific heats and mayer's relation
- Difficulty
- Easy
- Year
- 2025
Solution
Correct Answer:
R
Connecting the two principal molar specific heats of an ideal gas, Mayer's relation states Cp−Cv=R, where R is the universal gas constant. The physical reason is that heating a gas at constant volume raises only its internal energy, while heating at constant pressure also requires the gas to do work PΔV on its surroundings as it expands. The extra heat needed per mole per kelvin for this expansion work is exactly R. Therefore the difference equals R. The option R/2 wrongly associates the difference with a single degree of freedom. The option 2R doubles the expansion work, which has no physical basis. The option 3R/2 confuses the difference with the constant-volume specific heat of a monatomic gas. This is the standard NCERT result derived from the first law of thermodynamics applied to ideal gases. As a check, both Cp and Cv depend on degrees of freedom, yet their difference is universally R for every ideal gas, regardless of molecular structure.
This easy difficulty physics question is from the chapter kinetic theory of gases, covering the topic of specific heats and mayer's relation. It appeared in the 2025 exam.
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