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Specific Heats And Mayer's Relation

Easyphysics

For one mole of any ideal gas, the difference between the molar specific heat at constant pressure and that at constant volume equals which fundamental quantity?

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About This Question

Subject
physics
Chapter
kinetic theory of gases
Topic
specific heats and mayer's relation
Difficulty
Easy
Year
2025
Tags
Mayer's relationspecific heatuniversal gas constantfirst lawexpansion work

Solution

Correct Answer:

R

Connecting the two principal molar specific heats of an ideal gas, Mayer's relation states , where is the universal gas constant. The physical reason is that heating a gas at constant volume raises only its internal energy, while heating at constant pressure also requires the gas to do work on its surroundings as it expands. The extra heat needed per mole per kelvin for this expansion work is exactly . Therefore the difference equals . The option wrongly associates the difference with a single degree of freedom. The option doubles the expansion work, which has no physical basis. The option confuses the difference with the constant-volume specific heat of a monatomic gas. This is the standard NCERT result derived from the first law of thermodynamics applied to ideal gases. As a check, both and depend on degrees of freedom, yet their difference is universally for every ideal gas, regardless of molecular structure.

This easy difficulty physics question is from the chapter kinetic theory of gases, covering the topic of specific heats and mayer's relation. It appeared in the 2025 exam.

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