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Second Order Reaction

Mediumchemistry

For a second-order reaction with equal initial concentrations of reactants, the half-life is:

Select the correct option:

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About This Question

Subject
chemistry
Chapter
chemical kinetics
Topic
second order reaction
Difficulty
Medium
Year
2025
Tags
Second OrderHalf-LifeConcentration Dependence

Solution

Correct Answer:

Inversely proportional to initial concentration

For a reaction following Second-Order Kinetics, the integrated rate law is: At half-life (), . Substituting this into the equation:

  • Thus, the half-life is inversely proportional to the initial concentration. This distinguishes it from first-order reactions where is independent of concentration.

This medium difficulty chemistry question is from the chapter chemical kinetics, covering the topic of second order reaction. It appeared in the 2025 exam.

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