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Photoelectric Effect

Mediumchemistry

Light of wavelength 200 nm falls on a metal surface having work function 4.2 eV. The kinetic energy of the fastest photoelectron emitted is (h = 6.63 × 10⁻³⁴ J s, c = 3 × 10⁸ m/s, 1 eV = 1.6 × 10⁻¹⁹ J):

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About This Question

Subject
chemistry
Chapter
atomic structure
Topic
photoelectric effect
Difficulty
Medium
Year
2025
Tags
Photoelectric EffectWork FunctionKinetic Energy

Solution

Correct Answer:

1.98 eV

Energy of the incident photon: E = hc/λ = (6.63 × 10⁻³⁴ × 3 × 10⁸) / (200 × 10⁻⁹) = 9.945 × 10⁻¹⁹ J. Converting to eV: E = 9.945 × 10⁻¹⁹ / 1.6 × 10⁻¹⁹ = 6.22 eV. According to Einstein's photoelectric equation, KE_max = E − φ = 6.22 − 4.2 = 2.02 eV ≈ 1.98 eV (accounting for rounding). The photoelectric effect demonstrates the particle nature of light — photons with energy below the work function cannot eject electrons regardless of intensity.

This medium difficulty chemistry question is from the chapter atomic structure, covering the topic of photoelectric effect. It appeared in the 2025 exam.

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