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Passivation

Easychemistry

Passivation of iron in concentrated HNO₃ is due to formation of:

Select the correct option:

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About This Question

Subject
chemistry
Chapter
redox reactions and electrochemistry
Topic
passivation
Difficulty
Easy
Year
2025
Tags
PassivationIronNitric Acid

Solution

Correct Answer:

Oxide layer

Passivity is the state where a metal becomes chemically unreactive despite its position in the activity series.

  • Reaction with Iron: When Iron () is dipped in concentrated Nitric acid (), which is a powerful oxidizing agent, it reacts briefly but then stops.
  • Cause: The surface of the iron is oxidized to form an extremely thin, impervious, and protective oxide layer (specifically ).
  • This layer acts as a physical barrier, preventing the acid from reaching the underlying bulk metal. In contrast, dilute dissolves iron normally as it doesn't form this protective passive layer.

This easy difficulty chemistry question is from the chapter redox reactions and electrochemistry, covering the topic of passivation. It appeared in the 2025 exam.

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