Oxidation State Determination
Inside the complex anion present in potassium hexafluoridocobaltate, what is the oxidation state of cobalt given fluoride and potassium charges?
Select the correct option:
Solution
+3
The oxidation state of a central metal is obtained by setting the sum of all charges in the species equal to its overall charge. Potassium hexafluoridocobaltate is K3[CoF6]. Each potassium ion carries +1, and three of them contribute a total of +3, balancing the charge of the complex anion, which must therefore be -3. Inside that anion six fluoride ligands each carry -1, contributing -6. Letting the cobalt oxidation state be x, we write x + (6 × -1) = -3, so x - 6 = -3 and x = +3. Hence cobalt is in the +3 state. The value +2 ignores the correct anion charge, +4 wrongly assumes a -2 complex, and +6 absurdly cancels the fluoride charges entirely. This balance method is the routine NCERT approach to oxidation states in coordination compounds, and here it also explains why the complex is a high-spin fluoride species. Plausibility check: cobalt(III) is a very common and stable oxidation state in octahedral complexes, so the assignment is chemically reasonable.
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About This Question
- Subject
- chemistry
- Chapter
- coordination compounds
- Topic
- oxidation state determination
- Difficulty
- Easy
- Year
- 2025
Solution
Correct Answer:
+3
The oxidation state of a central metal is obtained by setting the sum of all charges in the species equal to its overall charge. Potassium hexafluoridocobaltate is K3[CoF6]. Each potassium ion carries +1, and three of them contribute a total of +3, balancing the charge of the complex anion, which must therefore be -3. Inside that anion six fluoride ligands each carry -1, contributing -6. Letting the cobalt oxidation state be x, we write x + (6 × -1) = -3, so x - 6 = -3 and x = +3. Hence cobalt is in the +3 state. The value +2 ignores the correct anion charge, +4 wrongly assumes a -2 complex, and +6 absurdly cancels the fluoride charges entirely. This balance method is the routine NCERT approach to oxidation states in coordination compounds, and here it also explains why the complex is a high-spin fluoride species. Plausibility check: cobalt(III) is a very common and stable oxidation state in octahedral complexes, so the assignment is chemically reasonable.
This easy difficulty chemistry question is from the chapter coordination compounds, covering the topic of oxidation state determination. It appeared in the 2025 exam.
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