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Nitro Reduction

Hardchemistry

Reduction of nitrobenzene with Sn/HCl gives initially:

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About This Question

Subject
chemistry
Chapter
nitrogen organics
Topic
nitro reduction
Difficulty
Hard
Year
2025
Tags
reduction pathwaynitrobenzene

Solution

Correct Answer:

Phenylhydroxylamine then aniline

  1. Reductive Sequence: Reduction of nitrobenzene involves multiple stages of electron and proton transfer.
  2. Path: (Nitrosobenzene) (Phenylhydroxylamine) (Aniline).
  3. Conditions: In an acidic medium with a strong reducing agent like or , the reaction proceeds all the way to aniline.
  4. Note: If the medium is neutral (), the reaction stops at Phenylhydroxylamine.

This hard difficulty chemistry question is from the chapter nitrogen organics, covering the topic of nitro reduction. It appeared in the 2025 exam.

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