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Molality And Mole Fraction

Mediumchemistry

A solution is prepared by dissolving 18 g of glucose ((\text{C}6\text{H}{12}\text{O}_6), molar mass = 180 g/mol) in 500 g of water. What is the molality of this solution?

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About This Question

Subject
chemistry
Chapter
some basic concepts in chemistry
Topic
molality and mole fraction
Difficulty
Medium
Year
2025
Tags
molalityconcentration unitsglucose solutionsolvent masscolligative properties

Solution

Correct Answer:

0.2 m

Molality is defined as the number of moles of solute per kilogram of solvent (not solution). It is temperature-independent and preferred for colligative property calculations. Moles of glucose (= 18/180 = 0.1) mol. Mass of solvent (water) (= 500) g (= 0.5) kg. Molality (m = 0.1/0.5 = 0.2) mol/kg (= 0.2) m. Option 0.1 m would result if the solvent were taken as 1 kg (1000 g), but here only 500 g is used. Option 0.5 m would result from incorrectly using 0.2 mol of glucose instead of 0.1 mol. Option 1.0 m would require either 0.1 mol in 100 g of water, or 0.5 mol in 500 g — neither matches. This question applies the NCERT definition of molality, distinguishing it from molarity which uses solution volume. Plausibility check: molality is expressed in mol/kg; (0.1 , \text{mol} \div 0.5 , \text{kg} = 0.2 , \text{m}), with consistent units throughout.

This medium difficulty chemistry question is from the chapter some basic concepts in chemistry, covering the topic of molality and mole fraction. It appeared in the 2025 exam.

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