Molality And Mole Fraction
A solution is prepared by dissolving 18 g of glucose ((\text{C}6\text{H}{12}\text{O}_6), molar mass = 180 g/mol) in 500 g of water. What is the molality of this solution?
Select the correct option:
Solution
0.2 m
Molality is defined as the number of moles of solute per kilogram of solvent (not solution). It is temperature-independent and preferred for colligative property calculations. Moles of glucose (= 18/180 = 0.1) mol. Mass of solvent (water) (= 500) g (= 0.5) kg. Molality (m = 0.1/0.5 = 0.2) mol/kg (= 0.2) m. Option 0.1 m would result if the solvent were taken as 1 kg (1000 g), but here only 500 g is used. Option 0.5 m would result from incorrectly using 0.2 mol of glucose instead of 0.1 mol. Option 1.0 m would require either 0.1 mol in 100 g of water, or 0.5 mol in 500 g — neither matches. This question applies the NCERT definition of molality, distinguishing it from molarity which uses solution volume. Plausibility check: molality is expressed in mol/kg; (0.1 , \text{mol} \div 0.5 , \text{kg} = 0.2 , \text{m}), with consistent units throughout.
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About This Question
- Subject
- chemistry
- Chapter
- some basic concepts in chemistry
- Topic
- molality and mole fraction
- Difficulty
- Medium
- Year
- 2025
Solution
Correct Answer:
0.2 m
Molality is defined as the number of moles of solute per kilogram of solvent (not solution). It is temperature-independent and preferred for colligative property calculations. Moles of glucose (= 18/180 = 0.1) mol. Mass of solvent (water) (= 500) g (= 0.5) kg. Molality (m = 0.1/0.5 = 0.2) mol/kg (= 0.2) m. Option 0.1 m would result if the solvent were taken as 1 kg (1000 g), but here only 500 g is used. Option 0.5 m would result from incorrectly using 0.2 mol of glucose instead of 0.1 mol. Option 1.0 m would require either 0.1 mol in 100 g of water, or 0.5 mol in 500 g — neither matches. This question applies the NCERT definition of molality, distinguishing it from molarity which uses solution volume. Plausibility check: molality is expressed in mol/kg; (0.1 , \text{mol} \div 0.5 , \text{kg} = 0.2 , \text{m}), with consistent units throughout.
This medium difficulty chemistry question is from the chapter some basic concepts in chemistry, covering the topic of molality and mole fraction. It appeared in the 2025 exam.
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