Markovnikov Rule
Major product of addition of HBr to propene (no peroxides) is:
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About This Question
- Subject
- chemistry
- Chapter
- hydrocarbons
- Topic
- markovnikov rule
- Difficulty
- Easy
- Year
- 2025
Solution
Correct Answer:
2-Bromopropane
- Electrophilic Addition: The reaction begins with the attack of the π-bond on the proton (H+) of HBr.
- Markovnikov's Rule: The proton adds to the carbon atom that already has more hydrogen atoms (the terminal CH2 group).
- Carbocation Intermediate: This results in the formation of a Secondary Carbocation (CH3−CH+−CH3), which is more stable than a primary one.
- Nucleophilic Attack: The bromide ion (Br−) then attacks the positively charged secondary carbon.
- Final Product: 2-Bromopropane is formed as the major product.
This easy difficulty chemistry question is from the chapter hydrocarbons, covering the topic of markovnikov rule. It appeared in the 2025 exam.
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