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Lassaigne's Test

Mediumchemistry

In Lassaigne's test for nitrogen, formation of Prussian blue color after treatment with FeSO4 and acidification indicates presence of:

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About This Question

Subject
chemistry
Chapter
purification and characterisation of organic compounds
Topic
lassaigne's test
Difficulty
Medium
Year
2025
Tags
Lassaigne TestNitrogen DetectionQualitative Analysis

Solution

Correct Answer:

Nitrogen only

During sodium fusion, nitrogen in the organic compound is converted to sodium cyanide. This reacts with Fe2+ to form ferrocyanide, which on oxidation/acidification gives ferric ferrocyanide (Prussian blue). Hence blue color indicates nitrogen in the original compound.

This medium difficulty chemistry question is from the chapter purification and characterisation of organic compounds, covering the topic of lassaigne's test. It appeared in the 2025 exam.

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