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Lanthanide Contraction

Mediumchemistry

Lanthanide contraction is responsible for:

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About This Question

Subject
chemistry
Chapter
classification of elements and periodicity in properties
Topic
lanthanide contraction
Difficulty
Medium
Year
2025
Tags
Lanthanide Contractionf-BlockAtomic Size

Solution

Correct Answer:

Similar sizes of Zr and Hf

Lanthanide Contraction is the steady decrease in the size of atoms/ions of lanthanide elements from to .

  • It is caused by the poor shielding of the nuclear charge by electrons.
  • A major consequence is that elements following the lanthanides (in the 3rd transition series) have atomic radii almost identical to their congeners in the 2nd transition series.
  • Example: Zirconium () and Hafnium () have nearly identical radii (), making them very similar in chemical properties.

This medium difficulty chemistry question is from the chapter classification of elements and periodicity in properties, covering the topic of lanthanide contraction. It appeared in the 2025 exam.

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