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Kolbe's Electrolysis

Mediumchemistry

Kolbe's electrolysis of sodium acetate produces:

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About This Question

Subject
chemistry
Chapter
hydrocarbons
Topic
kolbe's electrolysis
Difficulty
Medium
Year
2025
Tags
Kolbe's ElectrolysisDecarboxylationEthane

Solution

Correct Answer:

Ethane

Kolbe's Electrolytic Method prepares alkanes from sodium or potassium salts of carboxylic acids.

  • Process: Electrolysis of an aqueous solution of the salt.
  • Reaction at Anode: Acetate ion () loses an electron to form an acetate radical, which decarboxylates into a methyl radical (). Two methyl radicals combine to form Ethane ().
  • Hydrogen gas is liberated at the cathode.

This medium difficulty chemistry question is from the chapter hydrocarbons, covering the topic of kolbe's electrolysis. It appeared in the 2025 exam.

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