Kolbe's Electrolysis
Kolbe's electrolysis of sodium acetate produces:
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About This Question
- Subject
- chemistry
- Chapter
- hydrocarbons
- Topic
- kolbe's electrolysis
- Difficulty
- Medium
- Year
- 2025
Solution
Correct Answer:
Ethane
Kolbe's Electrolytic Method prepares alkanes from sodium or potassium salts of carboxylic acids.
- Process: Electrolysis of an aqueous solution of the salt.
- Reaction at Anode: Acetate ion (CH3COO−) loses an electron to form an acetate radical, which decarboxylates into a methyl radical (CH3.). Two methyl radicals combine to form Ethane (C2H6). 2CH3COO−−2e−→2CH3COO.→2CH3.+2CO2↑ CH3.+CH3.→CH3−CH3
- Hydrogen gas is liberated at the cathode.
This medium difficulty chemistry question is from the chapter hydrocarbons, covering the topic of kolbe's electrolysis. It appeared in the 2025 exam.
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