Isomerism
Mediumchemistry
Pair showing ionization isomerism among the following:
Select the correct option:
Solution
Incorrect! Answer:
[Co(NH3)5Br]SO4 and [Co(NH3)5SO4]Br
- Ionization Isomerism: Occurs when the composition of the coordination sphere ([…]) and the ionizable counter-ion are interchanged.
- Analysis:
- In [Co(NH3)5Br]SO4, SO42− is the counter-ion and gives a precipitate with BaCl2.
- In [Co(NH3)5SO4]Br, Br− is the counter-ion and gives a precipitate with AgNO3.
- Other pairs:
- The Cr pair represents hydrate isomerism (interchange of water).
- The Pt pair is the same molecule written differently.
- The Fe pair represents different oxidation states.
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About This Question
- Subject
- chemistry
- Chapter
- coordination compounds
- Topic
- isomerism
- Difficulty
- Medium
- Year
- 2025
This medium difficulty chemistry question is from the chapter coordination compounds, covering the topic of isomerism. It appeared in the 2025 exam. Practice this and similar questions to strengthen your understanding of coordination compounds concepts.
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