Isomerism
Mediumchemistry
Pair showing ionization isomerism among the following:
Select the correct option:
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About This Question
- Subject
- chemistry
- Chapter
- coordination compounds
- Topic
- isomerism
- Difficulty
- Medium
- Year
- 2025
Solution
Correct Answer:
[Co(NH3)5Br]SO4 and [Co(NH3)5SO4]Br
- Ionization Isomerism: Occurs when the composition of the coordination sphere ([…]) and the ionizable counter-ion are interchanged.
- Analysis:
- In [Co(NH3)5Br]SO4, SO42− is the counter-ion and gives a precipitate with BaCl2.
- In [Co(NH3)5SO4]Br, Br− is the counter-ion and gives a precipitate with AgNO3.
- Other pairs:
- The Cr pair represents hydrate isomerism (interchange of water).
- The Pt pair is the same molecule written differently.
- The Fe pair represents different oxidation states.
This medium difficulty chemistry question is from the chapter coordination compounds, covering the topic of isomerism. It appeared in the 2025 exam.
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