Ionization Enthalpy Anomaly
Why is the first ionization enthalpy of oxygen slightly lower than that of nitrogen, contrary to the general increase across a period?
Select the correct option:
Solution
Nitrogen has an extra-stable half-filled 2p subshell
First ionization enthalpy generally rises across a period, but exceptions occur where electronic configuration confers special stability. Nitrogen has the configuration 1s^2 2s^2 2p^3, with an exactly half-filled 2p subshell that is unusually stable due to symmetrical electron distribution and favourable exchange energy. Removing an electron from this stable arrangement requires extra energy. Oxygen has the configuration 1s^2 2s^2 2p^4, where the fourth 2p electron must pair up in an already occupied orbital, introducing electron-electron repulsion that makes it easier to remove. Consequently oxygen's first ionization enthalpy is slightly lower than nitrogen's. The option of smaller nuclear charge for oxygen is false, since oxygen has more protons. The option of more shells is wrong, as both are in period two. The option that nitrogen is a metal is incorrect. This half-filled stability anomaly is a key JEE Advanced periodicity point. Understanding ionization enthalpy anomaly in this way ties directly into the wider study of classification of elements and periodicity in properties, where the same reasoning recurs across many problems. Plausibility check: the analogous dip occurs between phosphorus and sulphur, confirming that half-filled stability causes the reversal.
🔒 Solution Hidden from View
Submit your answer to unlock the detailed step-by-step solution.
About This Question
- Subject
- chemistry
- Chapter
- classification of elements and periodicity in properties
- Topic
- ionization enthalpy anomaly
- Difficulty
- Hard
- Year
- 2025
Solution
Correct Answer:
Nitrogen has an extra-stable half-filled 2p subshell
First ionization enthalpy generally rises across a period, but exceptions occur where electronic configuration confers special stability. Nitrogen has the configuration 1s^2 2s^2 2p^3, with an exactly half-filled 2p subshell that is unusually stable due to symmetrical electron distribution and favourable exchange energy. Removing an electron from this stable arrangement requires extra energy. Oxygen has the configuration 1s^2 2s^2 2p^4, where the fourth 2p electron must pair up in an already occupied orbital, introducing electron-electron repulsion that makes it easier to remove. Consequently oxygen's first ionization enthalpy is slightly lower than nitrogen's. The option of smaller nuclear charge for oxygen is false, since oxygen has more protons. The option of more shells is wrong, as both are in period two. The option that nitrogen is a metal is incorrect. This half-filled stability anomaly is a key JEE Advanced periodicity point. Understanding ionization enthalpy anomaly in this way ties directly into the wider study of classification of elements and periodicity in properties, where the same reasoning recurs across many problems. Plausibility check: the analogous dip occurs between phosphorus and sulphur, confirming that half-filled stability causes the reversal.
This hard difficulty chemistry question is from the chapter classification of elements and periodicity in properties, covering the topic of ionization enthalpy anomaly. It appeared in the 2025 exam.
Looking for more practice? Explore all chemistry questions or browse classification of elements and periodicity in properties questions on RankGuru.