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Ionization Energy Trend

Hardchemistry

First ionization energy order (highest to lowest):

Select the correct option:

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About This Question

Subject
chemistry
Chapter
classification of elements and periodicity in properties
Topic
ionization energy trend
Difficulty
Hard
Year
2025
Tags
Ionization EnergyPeriodicityAnomaly

Solution

Correct Answer:

Ne > F > N > O

  1. General Trend: Ionization Energy (IE) generally increases from left to right across a period.
  2. Noble Gases: Neon () has a completely filled octet, making it extremely stable. It has the highest IE in its period.
  3. Halogens: Fluorine () is next with a very high effective nuclear charge.
  4. The Exception (N vs O):
    • Nitrogen has a configuration of (half-filled -subshell). This is inherently stable due to symmetry and exchange energy.
    • Oxygen is . Removing the electron relieves electron-electron repulsion in the orbital.
  5. Result: has a higher first IE than .
  6. Final Order: .

This hard difficulty chemistry question is from the chapter classification of elements and periodicity in properties, covering the topic of ionization energy trend. It appeared in the 2025 exam.

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