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Internal Energy And First Law

Easychemistry

A gas absorbs 450 J of heat and does 120 J of work on the surroundings during an expansion process. What is the change in internal energy of the gas?

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About This Question

Subject
chemistry
Chapter
chemical thermodynamics
Topic
internal energy and first law
Difficulty
Easy
Year
2025
Tags
first law of thermodynamicsinternal energyheat and worksign conventionexpansion process

Solution

Correct Answer:

330 J

The First Law of Thermodynamics states that the change in internal energy of a system equals the heat absorbed by the system minus the work done by the system on its surroundings: (\Delta \cup = q - w). Here, the gas absorbs heat so (q = +450) J (positive, heat flows into the system). The gas does work on the surroundings during expansion, so (w = +120) J (work done BY the system is positive). Applying the first law: (\Delta \cup = 450 - 120 = 330) J. Option 570 J is incorrect because it adds heat and work instead of subtracting work done by the system. Option -330 J would result if the gas were releasing heat instead of absorbing it. Option -570 J arises from both incorrect sign conventions applied simultaneously. This is a core NCERT Chapter 6 application of the first law of thermodynamics. Plausibility check: since heat absorbed exceeds work done, internal energy must increase, confirming (\Delta \cup > 0).

This easy difficulty chemistry question is from the chapter chemical thermodynamics, covering the topic of internal energy and first law. It appeared in the 2025 exam.

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