Internal Energy And First Law
A gas absorbs 450 J of heat and does 120 J of work on the surroundings during an expansion process. What is the change in internal energy of the gas?
Select the correct option:
Solution
330 J
The First Law of Thermodynamics states that the change in internal energy of a system equals the heat absorbed by the system minus the work done by the system on its surroundings: (\Delta \cup = q - w). Here, the gas absorbs heat so (q = +450) J (positive, heat flows into the system). The gas does work on the surroundings during expansion, so (w = +120) J (work done BY the system is positive). Applying the first law: (\Delta \cup = 450 - 120 = 330) J. Option 570 J is incorrect because it adds heat and work instead of subtracting work done by the system. Option -330 J would result if the gas were releasing heat instead of absorbing it. Option -570 J arises from both incorrect sign conventions applied simultaneously. This is a core NCERT Chapter 6 application of the first law of thermodynamics. Plausibility check: since heat absorbed exceeds work done, internal energy must increase, confirming (\Delta \cup > 0).
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About This Question
- Subject
- chemistry
- Chapter
- chemical thermodynamics
- Topic
- internal energy and first law
- Difficulty
- Easy
- Year
- 2025
Solution
Correct Answer:
330 J
The First Law of Thermodynamics states that the change in internal energy of a system equals the heat absorbed by the system minus the work done by the system on its surroundings: (\Delta \cup = q - w). Here, the gas absorbs heat so (q = +450) J (positive, heat flows into the system). The gas does work on the surroundings during expansion, so (w = +120) J (work done BY the system is positive). Applying the first law: (\Delta \cup = 450 - 120 = 330) J. Option 570 J is incorrect because it adds heat and work instead of subtracting work done by the system. Option -330 J would result if the gas were releasing heat instead of absorbing it. Option -570 J arises from both incorrect sign conventions applied simultaneously. This is a core NCERT Chapter 6 application of the first law of thermodynamics. Plausibility check: since heat absorbed exceeds work done, internal energy must increase, confirming (\Delta \cup > 0).
This easy difficulty chemistry question is from the chapter chemical thermodynamics, covering the topic of internal energy and first law. It appeared in the 2025 exam.
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