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Instantaneous Rate

Mediumchemistry

How is the instantaneous rate of a reaction obtained from a graph of concentration plotted against time during the course of the reaction?

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About This Question

Subject
chemistry
Chapter
chemical kinetics
Topic
instantaneous rate
Difficulty
Medium
Year
2025
Tags
instantaneous ratetangent slopeconcentration-time graphderivativeaverage versus instantaneous

Solution

Correct Answer:

From the slope of the tangent at that instant

The instantaneous rate of a reaction is the rate at a particular moment in time, and it is found from the slope of the tangent drawn to the concentration-time curve at that specific point. Mathematically it equals the derivative -d[reactant]/dt or +d[product]/dt evaluated at that instant, capturing how fast the concentration is changing right then rather than over an interval. The option of the area under the curve has no kinetic meaning for rate, as area relates to accumulated quantity. The y-intercept gives only the initial concentration, not a rate. The average of all points gives an average rate over the whole period, not the instantaneous value. Distinguishing instantaneous rate, obtained from the tangent, from average rate, obtained from a chord, is an important NCERT concept. Working through the logic step by step, rather than memorising the result, makes it clear why concentration-time graph governs the behaviour seen here. Carefully relating the data to the governing principle ensures the reasoning remains valid even when the numbers or species in the question are changed. Plausibility check: as the tangent becomes steeper the concentration is changing faster, correctly reflecting a higher instantaneous rate, which confirms the graphical method.

This medium difficulty chemistry question is from the chapter chemical kinetics, covering the topic of instantaneous rate. It appeared in the 2025 exam.

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