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Hydrogen Bonding

Easychemistry

Which of the following has the highest boiling point due to hydrogen bonding?

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About This Question

Subject
chemistry
Chapter
chemical bonding and molecular structure
Topic
hydrogen bonding
Difficulty
Easy
Year
2025
Tags
Hydrogen BondingBoiling PointIntermolecular Forces

Solution

Correct Answer:

H₂O

The boiling point of hydride group members usually increases down the group due to increasing van der Waals forces. However, is an anomaly.

  • Oxygen is highly electronegative and small in size, allowing it to form strong Intermolecular Hydrogen Bonds.
  • Each water molecule can form up to 4 hydrogen bonds, creating an extensive network.
  • cannot form effective hydrogen bonds as are larger and less electronegative.
  • Consequently, has a much higher boiling point () than its congeners.

This easy difficulty chemistry question is from the chapter chemical bonding and molecular structure, covering the topic of hydrogen bonding. It appeared in the 2025 exam.

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