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Half-life

Mediumchemistry

The half-life of a first-order radioactive decay is 30 minutes. What percentage of the original reactant remains after 90 minutes?

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About This Question

Subject
chemistry
Chapter
chemical kinetics
Topic
half-life
Difficulty
Medium
Year
2025
Tags
Half-LifeFirst OrderRadioactive Decay

Solution

Correct Answer:

12.5%

Number of half-lives elapsed = total time / t₁/₂ = 90 / 30 = 3 half-lives. For a first-order process, the fraction remaining after n half-lives = (1/2)ⁿ. Therefore, fraction remaining = (1/2)³ = 1/8 = 0.125 = 12.5%. This is a key property of first-order reactions — the fraction decomposed in each successive half-life is always 50% of whatever amount is present at that moment.

This medium difficulty chemistry question is from the chapter chemical kinetics, covering the topic of half-life. It appeared in the 2025 exam.

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