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Group 17 - Halogens

Mediumchemistry

Among halogens, which has the weakest X-X bond?

Select the correct option:

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About This Question

Subject
chemistry
Chapter
p-block elements
Topic
group 17 - halogens
Difficulty
Medium
Year
2025
Tags
HalogensBond StrengthFluorine Anomaly

Solution

Correct Answer:

F₂

Usually, bond strength decreases as atoms get larger. However, Fluorine () is an anomaly.

  • Weak Bond: The bond energy () is unexpectedly low, even lower than and .
  • Reason: Fluorine atoms are so small that the lone pair-lone pair repulsions between the non-bonding electrons of the two atoms are extremely high. This significantly weakens the single covalent bond.
  • Order of bond dissociation enthalpy: .

This medium difficulty chemistry question is from the chapter p-block elements, covering the topic of group 17 - halogens. It appeared in the 2025 exam.

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