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Group 16 Ozone

Mediumchemistry

Ozone acts as a powerful oxidising agent and readily decomposes to oxygen; what makes it thermodynamically unstable relative to dioxygen?

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About This Question

Subject
chemistry
Chapter
p-block elements
Topic
group 16 ozone
Difficulty
Medium
Year
2025
Tags
ozoneoxidising agentendothermic formationthermodynamic instabilitynascent oxygen

Solution

Correct Answer:

Its formation is endothermic, so it releases energy on decomposing

The reactivity and instability of ozone are linked to its thermodynamics. The formation of ozone from oxygen, 3O_2 → 2O_3, is endothermic with a positive enthalpy change, meaning ozone stores extra energy compared with ordinary dioxygen. Because of this stored energy, ozone readily decomposes back to oxygen, releasing energy and liberating a reactive nascent oxygen atom that makes ozone a powerful oxidising agent. The option that its formation is exothermic is incorrect, since the reverse holds. The option that it is a noble gas is false, as ozone is a reactive form of oxygen. The option that it has no oxygen atoms is absurd, since ozone is triatomic oxygen, O_3. The endothermic formation and consequent oxidising power of ozone are key NCERT facts for Group 16. A common JEE pitfall is to ignore the role of ozone, yet it is exactly this factor that distinguishes the correct answer from the tempting alternatives. It is worth emphasising that this is not a special case but a representative example of how group 16 ozone operates throughout p-block elements. Plausibility check: the positive enthalpy of formation directly explains both ozone's tendency to decompose and its strong oxidising action through released nascent oxygen, confirming the answer.

This medium difficulty chemistry question is from the chapter p-block elements, covering the topic of group 16 ozone. It appeared in the 2025 exam.

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