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Fajan's Rule

Mediumchemistry

According to Fajan's rules, which of the following compounds is most covalent?

Select the correct option:

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About This Question

Subject
chemistry
Chapter
chemical bonding and molecular structure
Topic
fajan's rule
Difficulty
Medium
Year
2025
Tags
Fajan's RuleCovalent CharacterPolarization

Solution

Correct Answer:

SiCl₄

Fajan's Rules state that the covalent character of an ionic bond increases with the polarizing power of the cation. Polarizing power increases with:

  1. Small Cationic Size.
  2. High Cationic Charge.
  • Compare: .
  • has the highest charge () and the smallest ionic radius among the series.
  • Therefore, it strongly polarizes the electron cloud of the ions, resulting in maximum covalent character.

This medium difficulty chemistry question is from the chapter chemical bonding and molecular structure, covering the topic of fajan's rule. It appeared in the 2025 exam.

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