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Entropy Concept

Easychemistry

Which process has ΔS > 0 at constant temperature?

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About This Question

Subject
chemistry
Chapter
chemical thermodynamics
Topic
entropy concept
Difficulty
Easy
Year
2025
Tags
EntropySpontaneityDisorder

Solution

Correct Answer:

Dissolution of NaCl in water

  1. Entropy (): A measure of the randomness or disorder of a system.
  2. Dissolution Process: When solid dissolves, the highly ordered crystal lattice breaks down, and ions () disperse into the solvent. This significantly increases randomness.
  3. Analysis of others:
    • Condensation: Gas Liquid (Order increases, ).
    • Freezing: Liquid Solid (Order increases, ).
    • Solid formation: Ions Solid (Order increases, ).
  4. Conclusion: Only the dissolution of NaCl results in a positive entropy change ().

This easy difficulty chemistry question is from the chapter chemical thermodynamics, covering the topic of entropy concept. It appeared in the 2025 exam.

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