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Elimination Vs Substitution

Mediumchemistry

2-Bromobutane on treatment with alcoholic KOH mainly gives:

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About This Question

Subject
chemistry
Chapter
organic compounds containing halogens
Topic
elimination vs substitution
Difficulty
Medium
Year
2025
Tags
EliminationAlcoholic KOHSaytzeff Rule

Solution

Correct Answer:

But-1-ene and But-2-ene

Alcoholic KOH favors beta-elimination (E2) in haloalkanes, removing HBr to form alkenes. Thus 2-bromobutane yields a mixture of but-1-ene and but-2-ene, with but-2-ene usually major by Saytzeff rule. Formation of alcohol is favored with aqueous KOH, not alcoholic KOH.

This medium difficulty chemistry question is from the chapter organic compounds containing halogens, covering the topic of elimination vs substitution. It appeared in the 2025 exam.

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