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Electrophiles And Nucleophiles

Easychemistry

Among the following reactive species, which one acts as a nucleophile because it can donate an electron pair to an electron-deficient centre?

Select the correct option:

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About This Question

Subject
chemistry
Chapter
some basic principles of organic chemistry
Topic
electrophiles and nucleophiles
Difficulty
Easy
Year
2025
Tags
nucleophileelectrophilelone pair donationLewis acidelectron-deficient centre

Solution

Correct Answer:

Nucleophiles are electron-rich species that supply a lone pair to form a new bond at an electron-poor carbon, while electrophiles are electron-deficient species that accept such a pair. The hydroxide ion carries a negative charge and three lone pairs on oxygen, making it a classic nucleophile that attacks positive or partially positive centres. Boron trifluoride is incorrect because boron has only six electrons and an empty orbital, so it accepts electron pairs and behaves as a Lewis acid, an electrophile. The nitronium ion is positively charged and electron-seeking, so it is an electrophile used in nitration, not a nucleophile. Aluminium chloride is an electron-deficient Lewis acid that accepts pairs, again an electrophile. The presence of an available lone pair and negative charge identifies OH^- as the nucleophile, matching NCERT definitions. Sanity check: a species that gives electrons must be electron-rich, and the negatively charged hydroxide fits this requirement perfectly.

This easy difficulty chemistry question is from the chapter some basic principles of organic chemistry, covering the topic of electrophiles and nucleophiles. It appeared in the 2025 exam.

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