Skip to content

Electron Gain Enthalpy

Mediumchemistry

Despite chlorine being below fluorine in the same group, why does chlorine have a more negative electron gain enthalpy than fluorine?

Select the correct option:

🔒 Solution Hidden from View

Submit your answer to unlock the detailed step-by-step solution.

About This Question

Subject
chemistry
Chapter
classification of elements and periodicity in properties
Topic
electron gain enthalpy
Difficulty
Medium
Year
2025
Tags
electron gain enthalpyhalogen anomalyelectron repulsionfluorine chlorine comparisonsmall atom effect

Solution

Correct Answer:

Fluorine's small size causes high electron-electron repulsion

Electron gain enthalpy is the energy change when an electron is added to a gaseous atom, and more negative values indicate a greater tendency to gain electrons. Although fluorine is the smaller and more electronegative atom, its 2p subshell is very compact, so adding an extra electron introduces strong electron-electron repulsion in the small valence shell. This repulsion offsets part of the energy released, making fluorine's electron gain enthalpy less negative than expected. Chlorine, being larger, accommodates the incoming electron with less repulsion, so its electron gain enthalpy is actually the most negative among the halogens. The option that fluorine has a larger size is factually wrong. The option that chlorine has fewer protons does not address the repulsion effect. The option that fluorine is a metal is incorrect, as it is a non-metal. This anomaly is a well-known NCERT periodicity point. Carefully relating the data to the governing principle ensures the reasoning remains valid even when the numbers or species in the question are changed. Understanding electron gain enthalpy in this way ties directly into the wider study of classification of elements and periodicity in properties, where the same reasoning recurs across many problems. Plausibility check: the same compactness explains why oxygen's electron gain enthalpy is less negative than sulphur's, confirming the reasoning.

This medium difficulty chemistry question is from the chapter classification of elements and periodicity in properties, covering the topic of electron gain enthalpy. It appeared in the 2025 exam.

Looking for more practice? Explore all chemistry questions or browse classification of elements and periodicity in properties questions on RankGuru.