Electron Gain Enthalpy
Despite chlorine being below fluorine in the same group, why does chlorine have a more negative electron gain enthalpy than fluorine?
Select the correct option:
Solution
Fluorine's small size causes high electron-electron repulsion
Electron gain enthalpy is the energy change when an electron is added to a gaseous atom, and more negative values indicate a greater tendency to gain electrons. Although fluorine is the smaller and more electronegative atom, its 2p subshell is very compact, so adding an extra electron introduces strong electron-electron repulsion in the small valence shell. This repulsion offsets part of the energy released, making fluorine's electron gain enthalpy less negative than expected. Chlorine, being larger, accommodates the incoming electron with less repulsion, so its electron gain enthalpy is actually the most negative among the halogens. The option that fluorine has a larger size is factually wrong. The option that chlorine has fewer protons does not address the repulsion effect. The option that fluorine is a metal is incorrect, as it is a non-metal. This anomaly is a well-known NCERT periodicity point. Carefully relating the data to the governing principle ensures the reasoning remains valid even when the numbers or species in the question are changed. Understanding electron gain enthalpy in this way ties directly into the wider study of classification of elements and periodicity in properties, where the same reasoning recurs across many problems. Plausibility check: the same compactness explains why oxygen's electron gain enthalpy is less negative than sulphur's, confirming the reasoning.
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About This Question
- Subject
- chemistry
- Chapter
- classification of elements and periodicity in properties
- Topic
- electron gain enthalpy
- Difficulty
- Medium
- Year
- 2025
Solution
Correct Answer:
Fluorine's small size causes high electron-electron repulsion
Electron gain enthalpy is the energy change when an electron is added to a gaseous atom, and more negative values indicate a greater tendency to gain electrons. Although fluorine is the smaller and more electronegative atom, its 2p subshell is very compact, so adding an extra electron introduces strong electron-electron repulsion in the small valence shell. This repulsion offsets part of the energy released, making fluorine's electron gain enthalpy less negative than expected. Chlorine, being larger, accommodates the incoming electron with less repulsion, so its electron gain enthalpy is actually the most negative among the halogens. The option that fluorine has a larger size is factually wrong. The option that chlorine has fewer protons does not address the repulsion effect. The option that fluorine is a metal is incorrect, as it is a non-metal. This anomaly is a well-known NCERT periodicity point. Carefully relating the data to the governing principle ensures the reasoning remains valid even when the numbers or species in the question are changed. Understanding electron gain enthalpy in this way ties directly into the wider study of classification of elements and periodicity in properties, where the same reasoning recurs across many problems. Plausibility check: the same compactness explains why oxygen's electron gain enthalpy is less negative than sulphur's, confirming the reasoning.
This medium difficulty chemistry question is from the chapter classification of elements and periodicity in properties, covering the topic of electron gain enthalpy. It appeared in the 2025 exam.
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