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Diene Stability

Mediumchemistry

Most stable among given dienes is:

Select the correct option:

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About This Question

Subject
chemistry
Chapter
hydrocarbons
Topic
diene stability
Difficulty
Medium
Year
2025
Tags
conjugationdiene

Solution

Correct Answer:

1,3-Butadiene

  1. Conjugated Dienes: Dienes where double bonds are separated by exactly one single bond ().
  2. Isolated Dienes: Dienes where double bonds are separated by two or more single bonds.
  3. Stability Cause: In conjugated dienes, there is overlap of -orbitals across the entire system, allowing -electron delocalization and resonance.
  4. Thermodynamics: Heat of hydrogenation shows that conjugated systems ( 1,3-butadiene) are significantly more stable (lower in energy) than isolated or cumulated ones.
  5. Cumulated Dienes: Dienes like 1,2-butadiene (allenes) where double bonds share a common carbon are the least stable due to inner carbon-carbon strain.

This medium difficulty chemistry question is from the chapter hydrocarbons, covering the topic of diene stability. It appeared in the 2025 exam.

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