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Conformational Analysis

Mediumchemistry

Most stable conformation of n-butane is:

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About This Question

Subject
chemistry
Chapter
hydrocarbons
Topic
conformational analysis
Difficulty
Medium
Year
2025
Tags
conformationsbutane

Solution

Correct Answer:

Anti staggered (methyls 180° apart)

  1. Types of Strain:
    • Torsional Strain: Repulsion between electron clouds of eclipsed bonds.
    • Steric Strain: Physical crowding of bulky groups ( methyl masses).
  2. Conformations of Butane:
    • Eclipsed (): Maximum strain (highest energy).
    • Gauche (): Staggered but methyl groups are close, causing some steric strain.
    • Anti (): Staggered and large methyl groups are as far apart as possible.
  3. Stability: The Anti-conformation maximizes distances between bulky methyl groups, minimizing both torsional and steric strain.
  4. Result: It is the global energy minimum (most stable).

This medium difficulty chemistry question is from the chapter hydrocarbons, covering the topic of conformational analysis. It appeared in the 2025 exam.

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