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Concentration Cell

Mediumchemistry

In a concentration cell with identical electrodes, driving force arises from:

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About This Question

Subject
chemistry
Chapter
electrochemistry
Topic
concentration cell
Difficulty
Medium
Year
2025
Tags
Concentration CellElectrochemicalGradient

Solution

Correct Answer:

Difference in ion concentration

  1. Definition: A cell consisting of two half-cells with identical electrodes and identical electrolytes, but at different concentrations.
  2. Standard Potential: Since the electrodes are the same (), .
  3. Operating Potential: Using the Nernst equation: .
  4. Work: The cell performs work as it tries to equalize the concentrations of the two half-cells (moving towards maximum entropy).
  5. Rule: For a positive , the more concentrated solution must be the cathode.

This medium difficulty chemistry question is from the chapter electrochemistry, covering the topic of concentration cell. It appeared in the 2025 exam.

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