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Classification Of Halides

Easychemistry

A halogen atom is attached to an sp3 carbon that is itself bonded directly to a carbon-carbon double bond; how is such a halide classified?

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About This Question

Subject
chemistry
Chapter
organic compounds containing halogens
Topic
classification of halides
Difficulty
Easy
Year
2025
Tags
allylic halidevinylic halideclassification of haloalkanessp3 carboncarbon-carbon double bond

Solution

Correct Answer:

Allylic halide

Halogen-containing organic compounds are classified by the hybridisation and environment of the carbon holding the halogen. When the halogen sits on an sp3 carbon that is adjacent to a carbon-carbon double bond, the compound is an allylic halide, because the carbon next to the C=C bond is called the allylic position. A vinylic halide is wrong because in that case the halogen would be bonded directly to the sp2 carbon of the double bond itself, not to the neighbouring sp3 carbon. An aryl halide is incorrect since it requires the halogen to be attached to an aromatic ring carbon. A benzylic halide is wrong because that needs the halogen on an sp3 carbon attached to a benzene ring, not to an open-chain alkene. This classification follows the NCERT treatment of haloalkanes and haloarenes and explains why allylic systems show enhanced SN1 reactivity through resonance stabilisation of the allyl cation. Sanity check: the carbon bearing the halogen is sp3 and one bond away from C=C, which is precisely the allylic description.

This easy difficulty chemistry question is from the chapter organic compounds containing halogens, covering the topic of classification of halides. It appeared in the 2025 exam.

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