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Chloroform

Easychemistry

Chloroform (CHCl₃) is stored in dark bottles because:

Select the correct option:

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About This Question

Subject
chemistry
Chapter
organic compounds containing halogens
Topic
chloroform
Difficulty
Easy
Year
2025
Tags
ChloroformPhosgeneStorage

Solution

Correct Answer:

It oxidizes to phosgene (COCl₂) in light

Chloroform () reacts slowly with oxygen in the presence of light to form Phosgene (), an extremely poisonous gas. Reaction:

  • To prevent this:
  1. It is stored in well-filled, dark-colored bottles to exclude light and air.
  2. A small amount () of Ethanol is added. Ethanol reacts with any phosgene formed to produce non-toxic diethyl carbonate.

This easy difficulty chemistry question is from the chapter organic compounds containing halogens, covering the topic of chloroform. It appeared in the 2025 exam.

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