Catalysis
How does a positive catalyst increase the rate of a chemical reaction without itself being consumed in the overall process?
Select the correct option:
Solution
By providing an alternative path of lower activation energy
A catalyst speeds up a reaction by providing an alternative reaction pathway that has a lower activation energy than the uncatalysed route. Because a greater fraction of molecules possess energy exceeding this reduced barrier at a given temperature, both the forward and reverse rates increase, and the reaction reaches equilibrium faster. The catalyst participates in intermediate steps but is regenerated, so it is not consumed overall. The option of increasing activation energy describes a negative effect and would slow the reaction. Raising temperature is a separate factor and is not how a catalyst works at constant temperature. Shifting the equilibrium is incorrect because a catalyst speeds both directions equally and leaves the equilibrium position and the value of K unchanged. This mechanism, illustrated by energy-profile diagrams, is a central NCERT concept. Plausibility check: a lower barrier necessarily increases the rate constant through the Arrhenius factor while leaving the thermodynamic equilibrium untouched, consistent with the chosen answer.
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About This Question
- Subject
- chemistry
- Chapter
- chemical kinetics
- Topic
- catalysis
- Difficulty
- Easy
- Year
- 2025
Solution
Correct Answer:
By providing an alternative path of lower activation energy
A catalyst speeds up a reaction by providing an alternative reaction pathway that has a lower activation energy than the uncatalysed route. Because a greater fraction of molecules possess energy exceeding this reduced barrier at a given temperature, both the forward and reverse rates increase, and the reaction reaches equilibrium faster. The catalyst participates in intermediate steps but is regenerated, so it is not consumed overall. The option of increasing activation energy describes a negative effect and would slow the reaction. Raising temperature is a separate factor and is not how a catalyst works at constant temperature. Shifting the equilibrium is incorrect because a catalyst speeds both directions equally and leaves the equilibrium position and the value of K unchanged. This mechanism, illustrated by energy-profile diagrams, is a central NCERT concept. Plausibility check: a lower barrier necessarily increases the rate constant through the Arrhenius factor while leaving the thermodynamic equilibrium untouched, consistent with the chosen answer.
This easy difficulty chemistry question is from the chapter chemical kinetics, covering the topic of catalysis. It appeared in the 2025 exam.
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