Carbocation Stability
Easychemistry
Correct order of carbocation stability:
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Solution
Incorrect! Answer:
(CH3)3C+ > (CH3)2CH+ > CH3CH2+ > CH3+
- Carbocation Stability: Factors that stabilize the positive charge on carbon include the inductive effect (+I) and hyperconjugation.
- Inductive Effect: Alkyl groups are electron-donating, helping to neutralize and spread the positive charge.
- Hyperconjugation: Also known as 'no-bond resonance', it involves the overlap of Ο-orbitals of CβH bonds with the empty p-orbital of the carbocation.
- Counting Ξ±-hydrogens:
- Tertiary ((CH3β)3βC+): 9 Ξ±-hydrogens.
- Secondary ((CH3β)2βCH+): 6 Ξ±-hydrogens.
- Primary (CH3βCH2+β): 3 Ξ±-hydrogens.
- Methyl (CH3+β): 0 Ξ±-hydrogens.
- Conclusion: Order is 3β>2β>1β> Methyl.
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About This Question
- Subject
- chemistry
- Chapter
- basic organic principles
- Topic
- carbocation stability
- Difficulty
- Easy
- Year
- 2025
Solution
Correct Answer:
(CH3)3C+ > (CH3)2CH+ > CH3CH2+ > CH3+
- Carbocation Stability: Factors that stabilize the positive charge on carbon include the inductive effect (+I) and hyperconjugation.
- Inductive Effect: Alkyl groups are electron-donating, helping to neutralize and spread the positive charge.
- Hyperconjugation: Also known as 'no-bond resonance', it involves the overlap of Ο-orbitals of CβH bonds with the empty p-orbital of the carbocation.
- Counting Ξ±-hydrogens:
- Tertiary ((CH3β)3βC+): 9 Ξ±-hydrogens.
- Secondary ((CH3β)2βCH+): 6 Ξ±-hydrogens.
- Primary (CH3βCH2+β): 3 Ξ±-hydrogens.
- Methyl (CH3+β): 0 Ξ±-hydrogens.
- Conclusion: Order is 3β>2β>1β> Methyl.
This easy difficulty chemistry question is from the chapter basic organic principles, covering the topic of carbocation stability. It appeared in the 2025 exam.
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