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Carbocation Stability

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Correct order of carbocation stability:

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About This Question

Subject
chemistry
Chapter
basic organic principles
Topic
carbocation stability
Difficulty
Easy
Year
2025
Tags
carbocationstability

Solution

Correct Answer:

(CH3)3C+ > (CH3)2CH+ > CH3CH2+ > CH3+

  1. Carbocation Stability: Factors that stabilize the positive charge on carbon include the inductive effect () and hyperconjugation.
  2. Inductive Effect: Alkyl groups are electron-donating, helping to neutralize and spread the positive charge.
  3. Hyperconjugation: Also known as 'no-bond resonance', it involves the overlap of -orbitals of bonds with the empty -orbital of the carbocation.
  4. Counting -hydrogens:
    • Tertiary (): -hydrogens.
    • Secondary (): -hydrogens.
    • Primary (): -hydrogens.
    • Methyl (): -hydrogens.
  5. Conclusion: Order is Methyl.

This easy difficulty chemistry question is from the chapter basic organic principles, covering the topic of carbocation stability. It appeared in the 2025 exam.

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