Bohr's Model
The wavelength of the first line in the Balmer series of hydrogen spectrum is 656 nm. The wavelength of the second line of this series is approximately:
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Solution
486 nm
The wavelength of spectral lines is given by the Rydberg Formula: Ξ»1β=RHβ(n12β1ββn22β1β) For the Balmer Series, n1β=2.
- First Line (HΞ±β line): Transition from n2β=3βn1β=2. 6561β=RHβ(221ββ321β)=RHβ(41ββ91β)=RHβ(365β)
- Second Line (HΞ²β line): Transition from n2β=4βn1β=2. Ξ»2β1β=RHβ(221ββ421β)=RHβ(41ββ161β)=RHβ(163β) Dividing Eq. 1 by Eq. 2: 656Ξ»2ββ=3/165/36β=365βΓ316β=2720β Ξ»2β=656Γ2720ββ485.9β486Β nm
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About This Question
- Subject
- chemistry
- Chapter
- atomic structure
- Topic
- bohr's model
- Difficulty
- Hard
- Year
- 2025
Solution
Correct Answer:
486 nm
The wavelength of spectral lines is given by the Rydberg Formula: Ξ»1β=RHβ(n12β1ββn22β1β) For the Balmer Series, n1β=2.
- First Line (HΞ±β line): Transition from n2β=3βn1β=2. 6561β=RHβ(221ββ321β)=RHβ(41ββ91β)=RHβ(365β)
- Second Line (HΞ²β line): Transition from n2β=4βn1β=2. Ξ»2β1β=RHβ(221ββ421β)=RHβ(41ββ161β)=RHβ(163β) Dividing Eq. 1 by Eq. 2: 656Ξ»2ββ=3/165/36β=365βΓ316β=2720β Ξ»2β=656Γ2720ββ485.9β486Β nm
This hard difficulty chemistry question is from the chapter atomic structure, covering the topic of bohr's model. It appeared in the 2025 exam.
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