Skip to content

Atomic Radius Down A Group

Easychemistry

Why does atomic radius increase down a group even though the nuclear charge also increases with each successive element?

Select the correct option:

🔒 Solution Hidden from View

Submit your answer to unlock the detailed step-by-step solution.

About This Question

Subject
chemistry
Chapter
classification of elements and periodicity in properties
Topic
atomic radius down a group
Difficulty
Easy
Year
2025
Tags
atomic radiusgroup trendshell additionshielding effectnuclear charge

Solution

Correct Answer:

Addition of new shells outweighs the rise in nuclear charge

Atomic radius down a group is governed by two competing factors: the addition of new electron shells and the increase in nuclear charge. Each step down a group adds a new principal energy shell, placing the outermost electrons significantly farther from the nucleus. Although the nuclear charge also rises, the added inner shells provide substantial shielding that reduces the net pull on the valence electrons. The shell-addition effect dominates, so the atomic radius increases steadily down the group. The option that shielding decreases is wrong, because additional inner shells increase shielding. The option that protons are removed is impossible. The option that electrons are removed contradicts the addition of electrons down a group. This dominance of shell number over nuclear charge is a key NCERT periodicity concept. Plausibility check: the radius increases markedly from lithium to caesium in Group 1, demonstrating that adding shells outweighs the growing nuclear charge.

This easy difficulty chemistry question is from the chapter classification of elements and periodicity in properties, covering the topic of atomic radius down a group. It appeared in the 2025 exam.

Looking for more practice? Explore all chemistry questions or browse classification of elements and periodicity in properties questions on RankGuru.